Difluorophosphoric acid

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Difluorophosphoric acid
HPO2F2.svg
Names
IUPAC name
Difluorophosphinic acid [1]
Other names
  • Difluorophosphoric acid
  • Fluophosphoric acid [1]
  • Phosphorodifluoridic acid [1]
Identifiers
3D model (JSmol)
ECHA InfoCard 100.034.005 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 237-421-6
PubChem CID
UNII
UN number 1768
  • InChI=1S/F2HO2P/c1-5(2,3)4/h(H,3,4)
    Key: DGTVXEHQMSJRPE-UHFFFAOYSA-N [1]
  • OP(=O)(F)F
Properties
HPO2F2
Molar mass 101.977 g·mol−1
AppearanceColorless liquid [1]
Density 1.583 g/cm3 [1] [2]
Melting point −96.5 °C (−141.7 °F; 176.7 K) [2]
Boiling point 115.9 °C (240.6 °F; 389.0 K) [2]
Structure
Tetrahedral at phosphorus atom
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Corrosive to living tissue
GHS labelling:
GHS-pictogram-acid.svg
Danger
H314
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Difluorophosphoric acid is an inorganic compound with the formula HPO2F2. It is a mobile colorless strongly fuming liquid. [1] The acid has limited applications, in part because it is thermally and hydrolytically unstable. [3] Difluorophosphoric acid is corrosive to glass, fabric, metals and living tissue. [1]

A method to make pure difluorphosphoric acid involves heating phosphoryl fluoride with fluorophosphoric acid and separating the product by distillation: [4]

POF3 + H2PO3F → 2 HPO2F2

It is prepared by hydrolysis of phosphoryl fluoride:

POF3 + H2O → HPO2F2 + HF

Further hydrolysis gives fluorophosphoric acid:

HPO2F2 + H2O → H2PO3F + HF

Complete hydrolysis gives phosphoric acid:

H2PO3F + H2O → H3PO4 + HF

The salts of difluorophosphoric acid are known as difluorophosphates.

Related Research Articles

In chemistry, a salt is a chemical compound consisting of an ionic assembly of positively charged cations and negatively charged anions, which results in a compound with no net electric charge. A common example is table salt, with positively charged sodium ions and negatively charged chloride ions.

<span class="mw-page-title-main">Oxygen difluoride</span> Chemical compound

Oxygen difluoride is a chemical compound with the formula OF2. As predicted by VSEPR theory, the molecule adopts a "bent" molecular geometry. It is strong oxidizer and has attracted attention in rocketry for this reason. With a boiling point of -144.75 °C, OF2 is the most volatile (isolable) triatomic compound. The compound is one of many known oxygen fluorides.

<span class="mw-page-title-main">Xenon hexafluoride</span> Chemical compound

Xenon hexafluoride is a noble gas compound with the formula XeF6. It is one of the three binary fluorides of xenon that have been studied experimentally, the other two being XeF2 and XeF4. All known are exergonic and stable at normal temperatures. XeF6 is the strongest fluorinating agent of the series. It is a colorless solid that readily sublimes into intensely yellow vapors.

<span class="mw-page-title-main">Hydrogen fluoride</span> Chemical compound

Hydrogen fluoride (fluorane) is an inorganic compound with chemical formula HF. It is a very poisonous, colorless gas or liquid that dissolves in water to yield an aqueous solution termed hydrofluoric acid. It is the principal industrial source of fluorine, often in the form of hydrofluoric acid, and is an important feedstock in the preparation of many important compounds including pharmaceuticals and polymers, e.g. polytetrafluoroethylene (PTFE). HF is also widely used in the petrochemical industry as a component of superacids. Due to strong and extensive hydrogen bonding, it boils at near room temperature, much higher than other hydrogen halides.

<span class="mw-page-title-main">Tetrafluoroborate</span> Anion

Tetrafluoroborate is the anion BF
4
. This tetrahedral species is isoelectronic with tetrafluoroberyllate (BeF2−
4
), tetrafluoromethane (CF4), and tetrafluoroammonium (NF+
4
) and is valence isoelectronic with many stable and important species including the perchlorate anion, ClO
4
, which is used in similar ways in the laboratory. It arises by the reaction of fluoride salts with the Lewis acid BF3, treatment of tetrafluoroboric acid with base, or by treatment of boric acid with hydrofluoric acid.

<span class="mw-page-title-main">Hexafluorosilicic acid</span> Octahedric silicon compound

Hexafluorosilicic acid is an inorganic compound with the chemical formula H
2
SiF
6
. Aqueous solutions of hexafluorosilicic acid consist of salts of the cation and hexafluorosilicate anion. These salts and their aqueous solutions are colorless.

<span class="mw-page-title-main">Aluminium fluoride</span> Chemical compound

Aluminium fluoride refers to inorganic compounds with the formula AlF3·xH2O. They are all colorless solids. Anhydrous AlF3 is used in the production of aluminium metal. Several occur as minerals.

<span class="mw-page-title-main">Zirconium tetrafluoride</span> Chemical compound

Zirconium(IV) fluoride describes members of a family inorganic compounds with the formula (ZrF4(H2O)x. All are colorless, diamagnetic solids. Anhydrous Zirconium(IV) fluoride' is a component of ZBLAN fluoride glass.

<span class="mw-page-title-main">Tungsten oxytetrafluoride</span> Chemical compound

Tungsten oxytetrafluoride is an inorganic compound with the formula WOF4. It is a colorless diamagnetic solid. The compound is one of many oxides of tungsten. It is usually encountered as product of the partial hydrolysis of tungsten hexafluoride.

<span class="mw-page-title-main">Hexafluorophosphate</span> Anion with the chemical formula PF6–

Hexafluorophosphate is an anion with chemical formula of [PF6]. It is an octahedral species that imparts no color to its salts. [PF6] is isoelectronic with sulfur hexafluoride, SF6, and the hexafluorosilicate dianion, [SiF6]2−, and hexafluoroantimonate [SbF6]. In this anion, phosphorus has a valence of 5. Being poorly nucleophilic, hexafluorophosphate is classified as a non-coordinating anion.

<span class="mw-page-title-main">Fluoroboric acid</span> Chemical compound

Fluoroboric acid or tetrafluoroboric acid is an inorganic compound with the simplified chemical formula H+[BF4]. Unlike other strong acids like H2SO4 or HClO4, the pure tetrafluoroboric acid does not exist. The term "fluoroboric acid" refers to a range of chemical compounds, depending on the solvent. The H+ in the simplified formula of fluoroboric acid represents the solvated proton. The solvent can be any suitable Lewis base. For instance, if the solvent is water, fluoroboric acid can be represented by the formula [H3O]+[BF4], although more realistically, several water molecules solvate the proton: [H(H2O)n]+[BF4]. The ethyl ether solvate is also commercially available, where the fluoroboric acid can be represented by the formula [H( 2O)n]+[BF4], where n is most likely 2.

<span class="mw-page-title-main">Vanadium pentafluoride</span> Chemical compound

Vanadium(V) fluoride is the inorganic compound with the chemical formula VF5. It is a colorless volatile liquid. It is a highly reactive compound, as indicated by its ability to fluorinate organic substances.

<span class="mw-page-title-main">Germanium tetrafluoride</span> Chemical compound

Germanium tetrafluoride (GeF4) is a chemical compound of germanium and fluorine. It is a colorless gas.

<span class="mw-page-title-main">Thiophosphoryl fluoride</span> Chemical compound

Thiophosphoryl fluoride is an inorganic molecular gas with formula PSF3 containing phosphorus, sulfur and fluorine. It spontaneously ignites in air and burns with a cool flame. The discoverers were able to have flames around their hands without discomfort, and called it "probably one of the coldest flames known". The gas was discovered in 1888.

Phosphoryl fluoride is a compound with the chemical formula POF3. It is a colorless gas that hydrolyzes rapidly.

<span class="mw-page-title-main">Sodium bifluoride</span> Chemical compound

Sodium bifluoride is the inorganic compound with the formula Na[HF2]. It is a salt of sodium cation and bifluoride anion. It is a white, water-soluble solid that decomposes upon heating. Sodium bifluoride is non-flammable, hygroscopic, and has a pungent smell. Sodium bifluoride has a number of applications in industry.

<span class="mw-page-title-main">Difluorophosphate</span> Chemical compound

Difluorophosphate or difluorodioxophosphate or phosphorodifluoridate is an anion with formula PO2F−2. It has a single negative charge and resembles perchlorate and monofluorosulfonate in shape and compounds. These ions are isoelectronic, along with tetrafluoroaluminate, phosphate, orthosilicate, and sulfate. It forms a series of compounds. The ion is toxic to mammals as it causes blockage to iodine uptake in the thyroid. However it is degraded in the body over several hours.

<span class="mw-page-title-main">Phosphoryl chloride difluoride</span> Chemical compound

Phosphoric chloride difluoride POF2Cl is a colourless gas. At one atmosphere pressure the gas condenses to a liquid at 3.1°C and freezes at −96.4. Alternate names are difluorophosphoryl chloride or phosphoryl chloride difluoride.

<span class="mw-page-title-main">Fluorophosphoric acid</span> Chemical compound

Fluorophosphoric acid is the inorganic compound with the formula H2PO3F. It is a colorless viscous liquid that solidifies to a rigid glass upon cooling at −78 °C (−108 °F).

<span class="mw-page-title-main">Hexafluoroarsenate</span> Chemical compound

The hexafluoroarsenate anion is a chemical species with formula AsF−6. Hexafluoroarsenate is relatively inert, being the conjugate base of the notional superacid hexafluoroarsenic acid.

References

  1. 1 2 3 4 5 6 7 8 https://pubchem.ncbi.nlm.nih.gov/compound/Difluorophosphoric-acid
  2. 1 2 3 Reed, William (September 1965). Studies of Difluorophosphoric Acid and its Alkali Metal Salts (Thesis). Retrieved 23 April 2023.
  3. Charles B. Lindahl; Tariq Mahmood (2000). "Fluorine Compounds, Inorganic, Phosphorus". Kirk‐Othmer Encyclopedia of Chemical Technology. doi:10.1002/0471238961.1608151912091404.a01. ISBN   0-471-23896-1.
  4. Lange, Willy; Livingston, Ralph (March 1950). "Studies of Fluorophosphoric Acids and their Derivatives. XIV. Preparation of Anhydrous Difluorophosphoric Acid". Journal of the American Chemical Society. 72 (3): 1280–1281. doi:10.1021/ja01159a057.